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Coinage metal complexes for near infrared emission and energy transfer photocatalysis

low energy IL-“through-space”-CT transitions in [Au(iPC)2]OTf (8) in the visible. The steric demand of the iPC leads to a high stability of 8 against air, moisture, or solvent attack, and ultralong-lived [...] from ligand-to-ligand charge transfer (1/3LLCT) states with quantum yields of up to 0.8 and exceptional kr of 0.8-1.9×10^6 s^-1 that are among the fastest for CuI emitters, outcompeting traditional triplet [...] highly efficient energy transfer (EnT) photocatalysis in a [2+2] styrene cycloaddition reaction using 8, which outperformed other established photocatalysts in comparison. In addition I also describe a series …