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11%, N2 13%, Figure S243), natural population analysis (NPA) charge analysis (P1 1.56, C1
ï0.70, N1 0.02, N4 ï0.15, Figure 2E) and NBO-based natural resonance theory (NRT) analysis (carbone
canonical structure [...] general ways to conceive of the electrophilic atomic carbon in a stable form, is in its
zerovalent [C(0)] form, flanked by two neutral donor groups. The term "carbones" was introduced by
Frenking and co-workers [...] exchange. 20
The challenges in using carbones as atomic carbon surrogates brought us to envision a C(0)-atom flanked
by two simple and labile groups, one of them specifically N2, as the ideal reagent to …