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An Air‐ and Moisture‐stable Zinc(II) Carbene Dithiolate Dimer Showing Fast Thermally Activated Delay
C, C3,5, Dipp), 122.3 (s, 4 C, PhS2), 84.5 (s, 2 C, NCC
carbene), 55.2 (s, 2 C, NC(CH3)2), 49.9 (s, 2 C, -CH2 ), 29.5 (s, 4 C, C(CH3)2), 29.4 (s, 4 C, CH(CH3)2, Dipp), 28.1 (s, 4 C, C(CH3)2), 27.3 (s, [...] MHz, CD2Cl2): δ [ppm]=7.53 (t, 3J(1H,1H)=7.8 Hz, 2H, H4, C6H3
iPr2), 7.39 (m, 4H, C6H4S2), 7.35 (d, 3J(1H,1H)=7.8 Hz, 4H, H3,5, C6H3
iPr2), 6.69 (m, 4H, C6H4S2), 2.77 (sept, 3J(1H,1H)=6.7 Hz, 4H, CHiPr), [...] 2.17 (s, 4H, CH2 ), 1.57 (s, 12H, (CH3)2), 1.48 (s, 12H, (CH3)2), 1.32 (d,
3J(1H,1H)=6.7 Hz, 12H, CH3
iPr), 1.23 d, 3J(1H,1H)=6.7 Hz, 12H, CH3 iPr). 13C NMR (125 MHz,
CD2Cl2): δ [ppm]=243.8 (s, 2 C, …