eldorado.tu-dortmund.de/items/8701347a-7f1b-4a62-8462-92e3c6055e66
Cycloadditions of diazoalkenes with P4 and tBuCP: access to diazaphospholes
lkyne (tBuCP) and white phosphorus (P4) to afford novel phosphorus heterocycles, 3H-1,2,4-diazamonophospholes and 1,2,3,4-diazadiphospholes. Both species represent rare examples of neutral heterophospholes [...] stellen Sie sich entsprechend darauf ein. Maintenance: at 2025-11-07 the system will be unavailable from 3 p.m. until 4 p.m. Please plan accordingly.
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New [...] holes. The mechanism of formation and the electronic structures of these formal (3+2) cycloaddition products were analyzed computationally. The new phospholes form structurally diverse coordination compounds …